Looking at complaints can be one way of surfacing pain points in a workflow. Often used by design...
Looking at complaints can be one way of surfacing pain points in a workflow. Often used by designers as input for customer journey maps.
But you also need to consider who is behind the complaint, who feels comfortable complaining and who is not given an opportunity to complain.
If you don't know what I mean by "not given an opportunity to complain", I'd urge you to read more about privilege, oppression and social norms.